kaiyun开云官方网站
团队力量

万贤楷     特聘研究员,博导

研究方向:物理化学;团簇化学;无机化学

联系方式:          Email:xkwan@scu.edu.cn

个人主页:点击进入

简历:

学习及工作经历

2021.06— 至今 kaiyun开云官方网站,特聘研究员,博士生导师

2018.10—2021.04 名古屋大学,JSPS特别研究员,合作导师:Mizuki Tada教授

2017.09—2018.09 南洋理工大学,博士后研究员,合作导师:楼雄文 教授

2011.09—2017.07 厦门大学化学化工公司,理学博士,导师:王泉明 教授

2007.09—2011.07 重庆大学化学化工公司,工学学士

主要研究方向

金属团簇化学

金属纳米团簇精准合成

金属纳米团簇发光与催化性质研究及应用

课题组诚招博士后、博士、硕士研究生、研究助理以及联合培养员工,欢迎对物理化学、团簇化学、无机化学、材料学、团簇催化、电化学、晶体学等感兴趣的员工加入本课题组。

主要工作业绩

主要从事金属纳米团簇精准合成、表征以及发光、催化应用等性质方面的研究。包括创新性的采用直接还原前驱体法和引入炔配体,首次合成并结构测定了系列结构与性质新颖的金属纳米团簇,原子水平揭示界面结构、建立构-效关系;首次原子水平揭示团簇催化中的配体效应,多孔限域纳米团簇电催化转化(电解水制氢、氧还原、二氧化碳还原等)。组成和结构确定且尺寸超小的金属纳米团簇,无论是对于研究基础科学问题还是广泛实际应用都具有重要的价值。截至目前已发表学术论文20余篇,以第一作者在Sci. Adv.J. Am. Chem. Soc.Angew. Chem. Int. Ed.Adv. Mater.Dalton. Trans.等杂志发表多篇论文,累积引用超过2200次,其中包括ESI高被引、VIPEditor Choicehot paper

主要奖励和荣誉

2023 入选开云全站中国有限公司青年科技学术带头人培育项目

2022 入选四川省天府峨眉计划青年项目

2021 入选开云全站中国有限公司双百B人才项目

2019 入选日本学术振兴会(JSPS)特别研究员项目

2017 厦门大学优秀毕业生

2015 博士研究生国家奖学金,卢嘉锡全国优秀研究生奖

2014 厦门大学“本栋”奖学金(校三大奖)

2012 硕士研究生国家奖学金

代表性成果 (获奖成果、专著、论文、专利)

1. Xian-Kai Wan, Jia-Qi Wang, and Quan-Ming Wang*. Ligand-Protected Au55 with a Novel Structure and Remarkable CO2 Electroreduction Performance, Angew. Chem. Int. Ed. 2021, 60, 20748. (hot paper)

2. Xian-Kai Wan, Gabor Samjeské*, Hirosuke Matsui, Chaoqi Chen, Satoshi Muratsugu, Mizuki Tada*. Ultrafine Pt-Ni Nanoparticles in Hollow Porous Carbon Spheres for Remarkable Oxygen Reduction Reaction Catalysis. Dalton. Trans. 2021, 50, 6811-6822. (back cover)

3. Xian-Kai Wan,# Hao Bin Wu,# Bu Yuan Guan, Deyan Luan, and Xiong Wen (David) Lou*. Confining Subnanometer Pt Clusters in Hollow Mesoporous Carbon Spheres for Boosting Hydrogen Evolution Activity, Adv. Mater. 2020, 32, e1901349. (ESI 高被引论文)

image description

4. Xian-Kai Wan, Jia-Qi Wang, Zi-Ang Nan and Quan-Ming Wang*. Ligand Effects in Catalysis by Atomically Precise Gold Nanoclusters, Sci. Adv. 2017, 3, e1701823. (ESI 高被引论文)

5. Xian-Kai Wan, Zong-Jie Guan, and Quan-Ming Wang*. Homoleptic Alkynyl-Protected Gold Nanoclusters: Au44(PhCC)28 and Au36(PhCC)24, Angew. Chem. Int. Ed. 2017, 56, 11494. (VIP文章)

6. Xian-Kai Wan, Xiao-Ling Cheng, Qing Tang, Ying-Zi Han, Guoxiang Hu,, De-En Jiang*, and Quan-Ming Wang*. Atomically Precise Bimetallic Au19Cu30 Nanocluster with an Icosidodecahedral Cu30 Shell and an Alkynyl–Cu Interface, J. Am. Chem. Soc. 2017, 139, 9451-9454.

7. Xian-Kai Wan, Wen-Wu Xu, Shang-Fu Yuan, Yi Gao*, Xiao-Cheng Zeng, and Quan-Ming Wang*. Near Infrared Emissive Alkynyl-Protected Au24 Nanocluster, Angew. Chem. Int. Ed. 2015 54, 9683-9686.

8. Xian-Kai Wan, Shang-Fu Yuan, Qing Tang, De-En Jiang*, and Quan-Ming Wang*. Alkynyl-Protected Au23 Nanocluster: A 12-Electron System, Angew. Chem. Int. Ed. 2015, 54, 5977-5980.

9. Xian-Kai Wan, Qing Tang, Shang-Fu Yuan, De-En Jiang*, and Quan-Ming Wang*. Au19 Nanocluster Featuring a V‑Shaped Alkynyl−Gold Motif, J. Am. Chem. Soc. 2015, 137, 652−655. (editor choice)

10. Xian-Kai Wan, Shang-Fu Yuan, Zhi-Wei Lin and Quan-Ming Wang*. Chiral Gold Nanocluster Au20 Protected by Tetradentate Phosphines, Angew. Chem. Int. Ed. 2014, 53, 5923-5926.

11. Xian-Kai Wan, Zhi-Wei Lin and Quan-Ming Wang*. Au20 Nanocluster Protected by Hemilabile Phosphines, J. Am. Chem. Soc. 2012, 134, 14750.

12. Shang-Fu Yuan, Heng-Wang Luyang, Zhen Lei, Xian-Kai Wan, Jiao-Jiao Li, Quan-Ming Wang* A stable well-defined copper hydride cluster consolidated with hemilabile phosphines. Chem. Commun. 2021, 57, 4315-4318.

13. Zhen Lei, Xian-Kai Wan, Shang-Fu Yuan, Zong-Jie Guan, Quan-Ming Wang*. Alkynyl Approach toward the Protection of Metal Nanoclusters, Acc. Chem. Res. 2018, 51, 2465.

14. Zhen Lei, Jiao-Jiao Li, Xian-Kai Wan, Wen-Han Zhang, Quan-Ming Wang*. Isolation and Total Structure Determination of an All AlkynylProtected Gold Nanocluster Au144. Angew. Chem. Int. Ed. 2018, 57, 8639.

15. Shang-Fu Yuan, Pei Li, Qing Tang, Xian-Kai Wan, Zi-Ang Nan, De-En Jiang*, and Quan-Ming Wang*. Alkynyl-protected silver nanoclusters featuring an anticuboctahedral kernel. Nanoscale 2017, 9, 11405-11409.

16. Zhen Lei, Xian-Kai Wan, Shang-Fu Yuan, Jia-Qi Wang and Quan-MingWang*. Alkynyl-Protected Gold and Gold-Silver Nanoclusters, Dalton. Trans. 2017, 46, 3427.

17. Wang Yu, Xian-Kai Wan, Li-Ting Ren, Hai-Feng Su, Gang Li, Sami Malola, Shui-Chao Lin, Zi-Chao Tang, Hannu Häkkinen, Boon K Teo, Quan-Ming Wang*, Nan-Feng Zheng*. Atomically Precise Alkynyl-Protected Metal Nanoclusters as a Model Catalyst: Observation of Promoting Effect of Surface Ligands on Catalysis by Metal Nanoparticles, J. Am. Chem. Soc. 2016, 138, 3278-3281.

18. Zong-Jie Guan, Jiu-Lian Zeng, Zi-Ang Nan, Xian-Kai Wan, Yu-Mei Lin*, Quan-Ming Wang*. Thiacalix[4]arene: New protection for metal nanoclusters, Sci. Adv. 2016, 2, e1600323.

19. Stefan Knoppe*, Qian-Fan Zhang, Xian-Kai Wan, Quan-Ming Wang, Lai-Sheng Wang, Thierry Verbiest. Second-Order Nonlinear Optical Scattering Properties of Phosphine-Protected Au20 Clusters, Ind. Eng. Chem. Res. 2016, 55, 10500-10506.

20. Xiao-Li Pei, Yang Yang, Zhen Lei, Shan-Shan Chang, Zong-Jie Guan, Xian-Kai Wan, Ting-Bin Wen, and Quan-Ming Wang*. Highly Active Gold(I)-Silver(I) Oxo Cluster Activating sp3 C-H Bonds of Methyl Ketones under Mild Conditions, J. Am. Chem. Soc. 2015, 137, 5520-5525.

关闭